||We report measurements from which we determine the spatial structure ofthe lunar contribution to night sky brightness, taken at the LSST site on Cerro Pachonin Chile. We use an array of six photodiodes with filters that approximate the LargeSynoptic Survey Telescope’su, g, r, i, z,andybands. We use the sun as a proxy forthe moon, and measure sky brightness as a function of zenith angle of the point onsky, zenith angle of the sun, and angular distance between the sun and the point onsky. We make a correction for the difference between the illumination spectrum of thesun and the moon. Since scattered sunlight totally dominates the daytime sky bright-ness, this technique allows us to cleanly determine the contribution to the (cloudless)night sky from backscattered moonlight, without contamination from other sourcesof night sky brightness. We estimate our uncertainty in the relative lunar night skybrightness vs. zenith and lunar angle to be between 0.3–0.7 mags depending on thepassband. This information is useful in planning the optimal execution of the LSSTsurvey, and perhaps for other astronomical observations as well. Although our pri-mary objective is to map out the angular structure and spectrum of the scattered lightfrom the atmosphere and particulates, we also make an estimate of the expected num-ber of scattered lunar photons per pixel per second in LSST, and find values that arein overall agreement with previous estimates.